Parents

• Francis of Spain, Duke of Cádiz
• Isabella II, queen of Spain

Marriages

1. Maria de las Mercedes de Orleáns y Bourbon, infanta of Spain
2. Maria Christina of Austria, queen of Spain

Children

Children from marriage 1

• No issue

Children from marriage 2

• Maria de las Mercedes de Bourbon, infanta of Spain
• Maria Teresa de Bourbon, infanta of Spain
• Alphonse XIII, King of Spain

Children with Elena Sanz y Martinez de Arrizala

• Alfonso Sanz y Martinez de Arrizala
• Fernando María Alfonso Martín Cristino Cesáreo Sanz y Martinez de Arrizala